Product ID:WHITE, 817A
MSDS Date:01/13/1989
FSC:8010
NIIN:00N009501
MSDS Number: CCBRT

E I DU PONT DE NEMOURS & CO INC

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-7515

Cage: B0589

E I DU PONT DE NEMOURS & CO

BRUSSEL, DE 19898 BE

Telephone: 32-(0)15-401.505

Cage: B0589

LAB STUDIES W/RATS HAVE

RTECS: 9999999ZZ

HIGH CONCS HAVE CAUSED EMBRYOTOXIC

RTECS: 9999999ZZ

LIVER & KIDNEY INJURY. CAN BE ABSORB THRU SKIN IN

RTECS: 9999999ZZ

OCCUP CHEM REPRO HAZ. SEEK CONSULT FROM APPROP HLTH

RTECS: 9999999ZZ

SAFE HANDLING AND EXPOSURE INFORMATION .

RTECS: 9999999ZZ

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

ALKYD RESIN

CAS: 63148-69-6

OSHA PEL N/K

ACGIH TLV: N/K

FATTY ACIDS,LINSEED-OIL,REACT PRODS

CAS: 96591-17-2

OSHA PEL N/K

ACGIH TLV: N/K

8 @

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM/200STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 4%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

36.7 @ 20C

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 12%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

15 @ 20C

CAS: 64742-89-8

OSHA PEL N/K

ACGIH TLV: N/K

25 @ 20C

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 21%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

10 @ 20C

CAS: 64742-94-5

RTECS: WF3100000

OSHA PEL N/K

ACGIH TLV: N/K

4.46

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

RECURRENT OVEREXP MAY

RTECS: 9999999ZZ

HAVE PRODUCED IRREGULAR HEARTBEATS IN ANIMALS &

RTECS: 9999999ZZ

HIGH AIRBORNE LEVELS HAVE EXHIBITED HIGH FREQUENCY

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE NOSE & THROAT
IRRIT. MAY CAUSE NERV SYS DEPRESS CHARACT BY HDCH, DIZZ, NAUS,
STAGG GAIT, CONFUSION, UNCON. REPORTS HAVE ASSOC RPTD & PRLNG
OVEREXP TO SOLV W/PERM BRAIN & NERV S YS DMG. EYE: MAY CAUSE
IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT
W/DISCOMFORT & DERM. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:TITANIUM DIOXIDE:IN LIFETIME INHAL
TEST, LUNG CANCERS WERE FOUND IN SOME RATS EXPOSED TO 250 MG/M3
RESP TITANIUM DUST. ANALYSIS OF TITANIUM DIOXIDE CONCS IN RAT'S
LUNGS SHOWED THAT LUNG CLEAR ANCE MECHANISM WAS OVERWHELMED & RSLTS
AT MASSIVE 250 MG/M3 LEVEL ARE NOT RELEVANT TO WORKPLACE. BUTYL
ACETATE:(SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP,
PREFERABLY MOUTH-TO-MOUTH. IF BRTHG DFCLT PERSISTS/OCCURS LATER,
CONSULT MD. EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN.
CALL MD. SKIN: WASH W/SOAP & WATER. IF IRRIT OCCURS, CONT MD.
INGEST: GI DISTRESS. IN THE UNLIKELY EVENT OF INGEST, CALL MD IMMED
& HAVE NAMES OF INGS AVAIL.

Flash Point Method:CC
Flash Point:>20F,>-7C
Lower Limits:0.7%
Upper Limits:13.1%
Extinguishing Media:USE FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO
PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS
FLAMM VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE
MIST/SPRAYS MAY BE FLAMM AT TEMPERATURES BELOW FLASH POINT.

Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT AND BREATHING OF VAPOR. CONFINE AND REMOVE
WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM HEAT, SPARKS, AND FLAME. CLOSE CONTAINER AFTER EACH USE.
GROUND CONTAINERS WHEN POURING.
Other Precautions:DO NOT STORE ABOVE 120F. DO NOT SAND, FLAME CUT,
BRAZE OR WELD DRY COATING WITHOUT A NIOSH/MSHA APPROVED RESPIRATOR
OR APPROPRIATE VENTILATION.

Respiratory Protection:DO NOT BREATHE VAPORS/MISTS. WEAR PROPERLY
FITTED VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA (TC-23C)
FOR USE W/PAINTS DURING APPLICATION & UNTIL ALL VAPORS & SPRAY
MISTS ARE EXHAUSTED. FOLLO W RESP MFR'S DIRECTIONS FOR RESP USE.
Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP
CONTAMINANTS < APPLIC OSHA REQUIREMENTS & OTHER SUGGESTED EXPOS
LIM.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:COVERALLS RECOMMENDED. EMERGENCY EYEWASH &
DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THORO AFTER HNDLG & BEFORE EATING/SMKNG.
PROT CREAMS MAY BE USED FOR EASE OF CLEAN UP, NOT FOR PROTECTION.
Supplemental Safety and Health
EFTS OF OVEREXP: RECURRENT OVEREXP MAY RSLT IN LIVER & KIDNEY INJURY.
METHYL ETHYL KETONE: HIGH CONCS HAVE CAUSED EMBRYOTOX EFTS IN LAB
ANIMALS. IT HAS BEEN DEMONSTRATED TO POTENTIATE (I.E., SHORTEN T
IME OF ONSET) PERIPHERAL NEUROPATHY CAUSED BY EITHER
N-HEXANE/METHYL N-BUTYL KETONE. LIQ SPLASHES IN EYE MAY (ING 11)

Boiling Pt:B.P. Text:>172F,>78C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.053
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MODERATE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:63.9

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKE, OXIDES OF HEAVY METALS.

Waste Disposal Methods:DO NOT ALLOW TO CONTAMINATE GROUND WATER
SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED
CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.